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Literature DB >> 15080663

C-C bond cleavage of acetonitrile by a dinuclear copper(II) cryptate.

Tongbu Lu¹, Xiaomei Zhuang, Yanwu Li, Shi Chen.

Abstract

The dinuclear copper(II) cryptate [Cu2L](ClO4)4 (1) cleaves the C-C bond of acetonitrile at room temperature to produce a cyanide bridged complex of [Cu2L(CN)](ClO4)3.2CH3CN.4H2O (2). The cleavage mechanism is presented on the basis of the results of the crystal structure of 2, electronic absorption spectra, ESI-MS spectroscopy, and GC spectra of 1, respectively.

Entities: Chemical

Year: 2004 PMID： 15080663 DOI： 10.1021/ja031874z

Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419

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Cited

4 in total

1. Reactivity of (Dicarboxamide)M(II)-OH (M = Cu, Ni) Complexes: Reaction with Acetonitrile to Yield M(II)-Cyanomethides.

Authors: Jacqui Tehranchi; Patrick J Donoghue; Christopher J Cramer; William B Tolman
Journal: Eur J Inorg Chem Date: 2013-08-01 Impact factor: 2.524

C-C bond cleavage of acetonitrile by a dinuclear copper(II) cryptate.

1. Reactivity of (Dicarboxamide)M(II)-OH (M = Cu, Ni) Complexes: Reaction with Acetonitrile to Yield M(II)-Cyanomethides.

2. In Situ Synthesis Mechanism and Photocatalytic Performance of Cyano-Bridged Cu (I)/Cu (II) Ultrathin Nanosheets.

3. Transformations of X (C, O, N)-CN Bonds: Cases of Selective X (C, O, N)-C Activation.

4. Synthetic Factors Governing Access to Tris(β-diketimine) Cyclophanes versus Tripodal Tri-β-aminoenones.