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Literature DB >> 15069193

Design of chiral ligands for asymmetric catalysis: from C2-symmetric P,P- and N,N-ligands to sterically and electronically nonsymmetrical P,N-ligands.

Abstract

For a long time, C(2)-symmetric ligands have dominated in asymmetric catalysis. More recently, nonsymmetrical modular P,N-ligands have been introduced. These ligands have been applied successfully in various metal-catalyzed reactions and, in many cases, have outperformed P,P- or N,N-ligands.

Entities: Chemical

Year: 2004 PMID： 15069193 PMCID： PMC395974 DOI： 10.1073/pnas.0307152101

Source DB: PubMed Journal: Proc Natl Acad Sci U S A ISSN： 0027-8424 Impact factor: 11.205

12 in total

1. Highly regio- and enantioselective Pd-catalyzed allylic alkylation and amination of monosubstituted allylic acetates with novel ferrocene P,N-ligands.

Authors: S L You; X Z Zhu; Y M Luo; X L Hou; L X Dai
Journal: J Am Chem Soc Date: 2001-08-01 Impact factor: 15.419

2. Probing electronic effects in the asymmetric Heck reaction with the BIPI ligands.

Authors: Carl A Busacca; Danja Grossbach; Regina C So; Erin M O'Brien; Earl M Spinelli
Journal: Org Lett Date: 2003-02-20 Impact factor: 6.005

3. Synthesis of versatile chiral N,P ligands derived from pyridine and quinoline.

Authors: William J Drury; Nicole Zimmermann; Martine Keenan; Masahiko Hayashi; Stefan Kaiser; Richard Goddard; Andreas Pfaltz
Journal: Angew Chem Int Ed Engl Date: 2004-01 Impact factor: 15.336

4. Privileged chiral catalysts.

Authors: Tehshik P Yoon; Eric N Jacobsen
Journal: Science Date: 2003-03-14 Impact factor: 47.728

5. New P,N ligands for asymmetric Ir-catalyzed reactions.

Authors: Tanasri Bunlaksananusorn; Kurt Polborn; Paul Knochel
Journal: Angew Chem Int Ed Engl Date: 2003-08-25 Impact factor: 15.336

6. Synthesis and application of chiral phosphino-imidazoline ligands: Ir-catalyzed enantioselective hydrogenation.

Authors: Frederik Menges; Markus Neuburger; Andreas Pfaltz
Journal: Org Lett Date: 2002-12-26 Impact factor: 6.005

7. Enantioselective hydrogenations of arylalkenes mediated by [Ir(cod) (JM-Phos) ]+ complexes.

Authors: D R Hou; J Reibenspies; T J Colacot; K Burgess
Journal: Chemistry Date: 2001-12-17 Impact factor: 5.236

8. Chiral imidazolylidine ligands for asymmetric hydrogenation of aryl alkenes.

Authors: M T Powell; D R Hou; M C Perry; X Cui; K Burgess
Journal: J Am Chem Soc Date: 2001-09-12 Impact factor: 15.419

9. Phospholane-oxazoline ligands for Ir-catalyzed asymmetric hydrogenation.

Authors: Wenjun Tang; Weimin Wang; Xumu Zhang
Journal: Angew Chem Int Ed Engl Date: 2003-02-24 Impact factor: 15.336

10. TADDOLs, Their Derivatives, and TADDOL Analogues: Versatile Chiral Auxiliaries.

Authors: Dieter Seebach; Albert K. Beck; Alexander Heckel
Journal: Angew Chem Int Ed Engl Date: 2001-01-05 Impact factor: 15.336

16 in total

1. Parameterization and Analysis of Peptide-Based Catalysts for the Atroposelective Bromination of 3-Arylquinazolin-4(3H)-ones.

Authors: Jennifer M Crawford; Elizabeth A Stone; Anthony J Metrano; Scott J Miller; Matthew S Sigman
Journal: J Am Chem Soc Date: 2018-01-10 Impact factor: 15.419

2. Diametric stereocontrol in dynamic catalytic reduction of racemic acyl phosphonates: divergence from α-keto ester congeners.

Authors: Michael T Corbett; Jeffrey S Johnson
Journal: J Am Chem Soc Date: 2013-01-08 Impact factor: 15.419

Review 3. Enantioselective C(sp³)‒H bond activation by chiral transition metal catalysts.

Authors: Tyler G Saint-Denis; Ru-Yi Zhu; Gang Chen; Qing-Feng Wu; Jin-Quan Yu
Journal: Science Date: 2018-02-16 Impact factor: 47.728

4. Palladium-catalyzed asymmetric construction of vicinal all-carbon quaternary stereocenters and its application to the synthesis of cyclotryptamine alkaloids.

Authors: Barry M Trost; Maksim Osipov
Journal: Angew Chem Int Ed Engl Date: 2013-07-03 Impact factor: 15.336

Review 5. Catalytic Asymmetric Synthesis of Butenolides and Butyrolactones.

Authors: Bin Mao; Martín Fañanás-Mastral; Ben L Feringa
Journal: Chem Rev Date: 2017-06-22 Impact factor: 60.622

6. Concise methods for the synthesis of chiral polyoxazolines and their application in asymmetric hydrosilylation.

Authors: Wei Jie Li; Zun Le Xu; Sheng Xiang Qiu
Journal: Beilstein J Org Chem Date: 2010-03-25 Impact factor: 2.883

Review 7. Developing ligands for palladium(II)-catalyzed C-H functionalization: intimate dialogue between ligand and substrate.

Authors: Keary M Engle; Jin-Quan Yu
Journal: J Org Chem Date: 2013-05-03 Impact factor: 4.354

Design of chiral ligands for asymmetric catalysis: from C2-symmetric P,P- and N,N-ligands to sterically and electronically nonsymmetrical P,N-ligands.

1. Highly regio- and enantioselective Pd-catalyzed allylic alkylation and amination of monosubstituted allylic acetates with novel ferrocene P,N-ligands.

2. Probing electronic effects in the asymmetric Heck reaction with the BIPI ligands.

3. Synthesis of versatile chiral N,P ligands derived from pyridine and quinoline.

4. Privileged chiral catalysts.

5. New P,N ligands for asymmetric Ir-catalyzed reactions.

6. Synthesis and application of chiral phosphino-imidazoline ligands: Ir-catalyzed enantioselective hydrogenation.

7. Enantioselective hydrogenations of arylalkenes mediated by [Ir(cod) (JM-Phos) ]+ complexes.

8. Chiral imidazolylidine ligands for asymmetric hydrogenation of aryl alkenes.

9. Phospholane-oxazoline ligands for Ir-catalyzed asymmetric hydrogenation.

10. TADDOLs, Their Derivatives, and TADDOL Analogues: Versatile Chiral Auxiliaries.

1. Parameterization and Analysis of Peptide-Based Catalysts for the Atroposelective Bromination of 3-Arylquinazolin-4(3H)-ones.

2. Diametric stereocontrol in dynamic catalytic reduction of racemic acyl phosphonates: divergence from α-keto ester congeners.

Review 3. Enantioselective C(sp³)‒H bond activation by chiral transition metal catalysts.

4. Palladium-catalyzed asymmetric construction of vicinal all-carbon quaternary stereocenters and its application to the synthesis of cyclotryptamine alkaloids.

Review 5. Catalytic Asymmetric Synthesis of Butenolides and Butyrolactones.

6. Concise methods for the synthesis of chiral polyoxazolines and their application in asymmetric hydrosilylation.

Review 7. Developing ligands for palladium(II)-catalyzed C-H functionalization: intimate dialogue between ligand and substrate.

8. Reducing Challenges in Organic Synthesis with Stereoselective Hydrogenation and Tandem Catalysis.

9. Aqua-chlorido-(2-{[6-(di-methyl-amino)-pyrimidin-4-yl]sulfan-yl}pyrimidine-4,6-di-amine)-copper(II) chloride hydrate.

10. A modular approach to neutral P,N-ligands: synthesis and coordination chemistry.

Review 3. Enantioselective C(sp3)‒H bond activation by chiral transition metal catalysts.

Review 5. Catalytic Asymmetric Synthesis of Butenolides and Butyrolactones.

Review 7. Developing ligands for palladium(II)-catalyzed C-H functionalization: intimate dialogue between ligand and substrate.

Review 3. Enantioselective C(sp³)‒H bond activation by chiral transition metal catalysts.