| Literature DB >> 14973631 |
Susana L H Rebelo1, Mário M Q Simões, M Graça P M S Neves, Artur M S Silva, José A S Cavaleiro.
Abstract
Efficient epoxidation, in very high conversions and selectivities, of aromatic hydrocarbons with hydrogen peroxide, in the presence of Mn(III) porphyrins [Mn(TDCPP)Cl, Mn(beta NO(2)TDCPP)Cl, Mn(TPFPP)Cl] as catalysts is described; naphthalene and anthracene afford the anti-1,2:3,4-arene dioxides whereas with phenanthrene the 9,10-oxide is obtained.Entities:
Year: 2004 PMID： 14973631 DOI： 10.1039/b313683c
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222