| Literature DB >> 14599181 |
Anette Yahav1, Israel Goldberg, Arkadi Vigalok.
Abstract
The synthesis and characterization of previously unknown palladium(II) and platinum(II) difluoro phosphine complexes are described. These complexes can be obtained either via a halide metathesis reaction with AgF in dichloromethane or by reacting the corresponding dimethyl complexes with XeF2. While the Pt(II) complexes can be prepared with both aryl- and alkyl-phosphine ligands, the stability of the Pd(II) complexes is limited to those having cis-oriented trialkyl phosphine ligands.Entities:
Year: 2003 PMID： 14599181 DOI： 10.1021/ja0377753
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419