Literature DB >> 14570467

Formation of the intermediate-spin iron(III) porphyrin complexes with (dxz, dyz)3(dxy)1(dz2)1 electron configuration.

Takanori Sakai1, Yoshiki Ohgo, Takahisa Ikeue, Masashi Takahashi, Masuo Takeda, Mikio Nakamura.   

Abstract

On the basis of the difference in meso-13C chemical shifts, we have concluded that the intermediate-spin iron(III) complexes with highly ruffled and highly saddled porphyrins have different electron configurations. While the latter has a conventional (dxy)2(dxz, dyz)2(dz2)1, the former adopts a novel (dxz, dyz)3(dxy)1(dz2)1.

Entities:  

Year:  2003        PMID： 14570467     DOI： 10.1021/ja030448a

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  3 in total

1.  Probing the oxyferrous and catalytically active ferryl states of Amphitrite ornata dehaloperoxidase by cryoreduction and EPR/ENDOR spectroscopy. Detection of compound I.

Authors:  Roman Davydov; Robert L Osborne; Muralidharan Shanmugam; Jing Du; John H Dawson; Brian M Hoffman
Journal:  J Am Chem Soc       Date:  2010-10-27       Impact factor: 15.419

2.  Effect of the Ruffled Porphyrin Ring on Electronic Structures: Structure and Characterization of [Fe(TalkylP)(OClO3)] and [Fe(TPrP)(THF)2]ClO4 (alkyl = Ethyl, Et and n-Propyl, Pr).

Authors:  Ming Li; Allen G Oliver; Teresa J Neal; Charles E Schulz; W Robert Scheidt
Journal:  J Porphyr Phthalocyanines       Date:  2013-01       Impact factor: 1.811

3.  Mössbauer, NMR, geometric, and electronic properties in S = 3/2 iron porphyrins.

Authors:  Yan Ling; Yong Zhang
Journal:  J Am Chem Soc       Date:  2009-05-13       Impact factor: 15.419
  3 in total

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