Literature DB >> 14535753

Cobalt-catalyzed three-component coupling reaction of alkyl halides, 1,3-dienes, and trimethylsilylmethylmagnesium chloride.

Keiya Mizutani1, Hiroshi Shinokubo, Koichiro Oshima.   

Abstract

[reaction: see text] A combination of CoCl(2) and 1,6-bis(diphenylphosphino)hexane catalyzes a novel three-component coupling reaction of alkyl bromides, 1,3-dienes, and silylmethylmagnesium chloride, yielding homoallylsilanes in good to excellent yields. The reaction involves a radical species from alkyl halides.

Entities:  

Year:  2003        PMID： 14535753     DOI： 10.1021/ol0356643

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  12 in total

1.  A palladium-catalyzed three-component cross-coupling of conjugated dienes or terminal alkenes with vinyl triflates and boronic acids.

Authors:  Longyan Liao; Ranjan Jana; Kaveri Balan Urkalan; Matthew S Sigman
Journal:  J Am Chem Soc       Date:  2011-03-30       Impact factor: 15.419

2.  Nickel-Catalyzed α-Carbonylalkylarylation of Vinylarenes: Expedient Access to γ,γ-Diarylcarbonyl and Aryltetralone Derivatives.

Authors:  Shekhar Kc; Roshan K Dhungana; Namrata Khanal; Ramesh Giri
Journal:  Angew Chem Int Ed Engl       Date:  2020-03-19       Impact factor: 15.336

3.  Enantioselective Radical Addition/Cross-Coupling of Organozinc Reagents, Alkyl Iodides, and Alkenyl Boron Reagents.

Authors:  Matteo Chierchia; Peilin Xu; Gabriel J Lovinger; James P Morken
Journal:  Angew Chem Int Ed Engl       Date:  2019-08-28       Impact factor: 15.336

4.  Catalytic Radical Domino Reactions in Organic Synthesis.

Authors:  Leanne J Sebren; James J Devery; Corey R J Stephenson
Journal:  ACS Catal       Date:  2014-02-07       Impact factor: 13.084

5.  An Expedient Route to 9-arylmethylanthracene Derivatives via Tandem Ni-catalyzed Alkene Dicarbofunctionalization and Acid-promoted Cyclization-aromatization.

Authors:  Doleshwar Niroula; Rishi R Sapkota; Roshan K Dhungana; Bijay Shrestha; Ramesh Giri
Journal:  Isr J Chem       Date:  2020-02-14       Impact factor: 3.333

6.  Ni(I)-Catalyzed β,δ-Vinylarylation of γ,δ-Alkenyl α-Cyanocarboxylic Esters via Contraction of Transient Nickellacycles.

Authors:  Roshan K Dhungana; Shekhar Kc; Prakash Basnet; Vivek Aryal; Lucas J Chesley; Ramesh Giri
Journal:  ACS Catal       Date:  2019-10-29       Impact factor: 13.700

7.  Transition Metal (Ni, Cu, Pd)-Catalyzed Alkene Dicarbofunctionalization Reactions.

Authors:  Laura M Wickham; Ramesh Giri
Journal:  Acc Chem Res       Date:  2021-08-12       Impact factor: 24.466

8.  Ni-catalysed regioselective 1,2-diarylation of unactivated olefins by stabilizing Heck intermediates as pyridylsilyl-coordinated transient metallacycles.

Authors:  Surendra Thapa; Roshan K Dhungana; Rajani Thapa Magar; Bijay Shrestha; Shekhar Kc; Ramesh Giri
Journal:  Chem Sci       Date:  2017-11-27       Impact factor: 9.825

9.  Organozinc pivalates for cobalt-catalyzed difluoroalkylarylation of alkenes.

Authors:  Xinyi Cheng; Xingchen Liu; Shengchun Wang; Ying Hu; Binjing Hu; Aiwen Lei; Jie Li
Journal:  Nat Commun       Date:  2021-07-16       Impact factor: 14.919

10.  Directed nickel-catalyzed 1,2-dialkylation of alkenyl carbonyl compounds.

Authors:  Joseph Derosa; Vincent A van der Puyl; Van T Tran; Mingyu Liu; Keary M Engle
Journal:  Chem Sci       Date:  2018-05-16       Impact factor: 9.825
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