| Literature DB >> 24587964 |
Leanne J Sebren1, James J Devery1, Corey R J Stephenson1.
Abstract
Catalytic radical-based domino reactions represent important advances in synthetic organic chemistry. Their development benefits synthesis by providing atom- and step-economical methods to complex molecules. Intricate combinations of radical, cationic, anionic, oxidative/reductive, and transition metal mechanistic steps result in cyclizations, additions, fragmentations, ring-expansions, and rearrangements. This Perspective summarizes recent developments in the field of catalytic domino processes.Entities:
Keywords: cascade; domino; photoredox; radical; tandem; transition metal
Year: 2014 PMID: 24587964 PMCID: PMC3935257 DOI: 10.1021/cs400995r
Source DB: PubMed Journal: ACS Catal Impact factor: 13.084