Literature DB >> 14518870

Synthesis of neutral nickel catalysts for ethylene polymerization--the influence of ligand size on catalyst stability.

Eric F Connor1, Todd R Younkin, Jason I Henderson, Andrew W Waltman, Robert H Grubbs.   

Abstract

A facile synthesis of nickel salicylaldimine complexes with labile dissociating ligands is described. In addition to producing highly active ethylene polymerization catalysts, important insights into the effect of ligand size on catalyst stability and information on the mechanism of polymerization are provided.

Entities:  

Year:  2003        PMID： 14518870     DOI： 10.1039/b306701g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

1.  Dinickel Bisphenoxyiminato Complexes for the Polymerization of Ethylene and α-Olefins.

Authors:  Madalyn Radlauer; Michael W Day; Theodor Agapie
Journal:  Organometallics       Date:  2012-03-08       Impact factor: 3.876

2.  (4Z)-4-[(2,6-Diisopropyl-anilino)(phen-yl)methyl-idene]-3-methyl-1-phenyl-1H-pyrazol-5(4H)-one.

Authors:  Shu-Ling Lai; Ching-Yao Chang
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2011-01-12

3.  Bis{1-[3-(diethyl-ammonio)-propyl-imino-meth-yl]naphthalen-2-olato}nickel(II) dinitrate.

Authors:  Xiao-Hui Ji; Jiu-Fu Lu
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2010-07-03

4.  cis-Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN(2))ethanamine-κN]palladium(II) dichloro-methane monosolvate.

Authors:  Collins Obuah; James Darkwa; Alfred Muller
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2012-07-21
  4 in total

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