Literature DB >> 12950193

Short metal-metal separations in a highly luminescent trimetallic Ag(I) complex stabilized by bridging NHC ligands.

Vincent J Catalano1, Mark A Malwitz.   

Abstract

Reaction of 1,3-bis(2-pyridinylmethyl)-1H-imidazolium salt, [H(pyCH(2))(2)im]X (X = BF(4)(-) or Cl(-)), with silver oxide in acetonitrile readily yields yellow-brown [((pyCH(2))(2)im)(2)Ag]X, 1.BF(4) or 1.Cl. The chloride salt crystallizes with 3.650 A intermolecular Ag...Ag interactions while 1.BF(4) shows no short intermolecular interaction. Addition of excess Ag(BF(4)) produces the homoleptic carbene bridged trimetallic species, [(mu-NHC)(3)Ag(3)](BF(4))(3), 2. This species contains very short Ag-Ag separations between 2.7249(10) and 2.7718(9) A. In solution, these complexes are photoluminescent.

Entities:  

Year:  2003        PMID： 12950193     DOI： 10.1021/ic034483u

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  4 in total

1.  A theobromine derived silver N-heterocyclic carbene: synthesis, characterization, and antimicrobial efficacy studies on cystic fibrosis relevant pathogens.

Authors:  Matthew J Panzner; Khadijah M Hindi; Brian D Wright; Jane B Taylor; Daniel S Han; Wiley J Youngs; Carolyn L Cannon
Journal:  Dalton Trans       Date:  2009-08-06       Impact factor: 4.390

2.  Shedding light on the photochemistry of coinage-metal phosphorescent materials: a time-resolved Laue diffraction study of an Ag(I)-Cu(I) tetranuclear complex.

Authors:  Katarzyna N Jarzembska; Radosław Kamiński; Bertrand Fournier; Elżbieta Trzop; Jesse D Sokolow; Robert Henning; Yang Chen; Philip Coppens
Journal:  Inorg Chem       Date:  2014-09-19       Impact factor: 5.165

3.  Bis{1,4-bis-[(3-butyl-imidazolium-1-yl)meth-yl]benzene}-silver(I) bis-(hexa-fluoridophosphate).

Authors:  Rosenani A Haque; Abbas Washeel; Siang Guan Teoh; Madhukar Hemamalini; Hoong-Kun Fun
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2010-09-25

4.  Blue-emitting acridine-tagged silver(i)-bis-N-heterocyclic carbene.

Authors:  Ganesan Prabusankar; Nirmala Muthukumaran; Moulali Vaddamanu; Gembali Raju; Kavitha Velappan; Arruri Sathyanarayana; Yamane Masaya; Shohei Sugiyama; Kyohei Hisano; Osamu Tsutsumi
Journal:  RSC Adv       Date:  2019-03-06       Impact factor: 4.036
  4 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.