| Literature DB >> 12914433 |
Margarita Paneque1, Cristina M Posadas, Manuel L Poveda, Nuria Rendón, Verónica Salazar, Enrique Oñate, Kurt Mereiter.
Abstract
A new route to irida-aromatic derivatives which consists of the oxidation of bicyclic compounds has been disclosed. The iridanaphthalene 3 experiences hydrolytic cleavage of the Ir-carboxylate moiety regenerating the bicyclic structure 5, whereas treatment of 5 with ClC(O)CO2Me yields back the metalla-aromatic 3.Entities:
Year: 2003 PMID： 12914433 DOI： 10.1021/ja035655p
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419