Literature DB >> 12837068

Mechanism and dynamics of azobenzene photoisomerization.

Thomas Schultz1, Jason Quenneville, Benjamin Levine, Alessandro Toniolo, Todd J Martínez, Stefan Lochbrunner, Michael Schmitt, James P Shaffer, Marek Z Zgierski, Albert Stolow.   

Abstract

The excited-state dynamics of trans-azobenzene were investigated by femtosecond time-resolved photoelectron spectroscopy and ab initio molecular dynamics. Two near-degenerate pipi* excited states, S2 and S3,4, were identified in a region hitherto associated with only one excited state. These results help to explain contradictory reports about the photoisomerization mechanism and the wavelength dependence of the quantum yield. A new model for the isomerization mechanism is proposed.

Entities:  

Year:  2003        PMID： 12837068     DOI： 10.1021/ja021363x

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  20 in total

1.  Unveiling the spatial distribution of molecular coherences at conical intersections by covariance X-ray diffraction signals.

Authors:  Stefano M Cavaletto; Daniel Keefer; Jérémy R Rouxel; Flavia Aleotti; Francesco Segatta; Marco Garavelli; Shaul Mukamel
Journal:  Proc Natl Acad Sci U S A       Date:  2021-06-01       Impact factor: 11.205

2.  Machine Learning for Electronically Excited States of Molecules.

Authors:  Julia Westermayr; Philipp Marquetand
Journal:  Chem Rev       Date:  2020-11-19       Impact factor: 60.622

3.  Photoisomerization transition state manipulation by entangled two-photon absorption.

Authors:  Bing Gu; Daniel Keefer; Flavia Aleotti; Artur Nenov; Marco Garavelli; Shaul Mukamel
Journal:  Proc Natl Acad Sci U S A       Date:  2021-11-23       Impact factor: 11.205

4.  Light-responsive biomaterials for ocular drug delivery.

Authors:  Hend A M Abdelmohsen; Nikki A Copeland; John G Hardy
Journal:  Drug Deliv Transl Res       Date:  2022-06-24       Impact factor: 4.617

5.  Twisting the phenyls in aryl diphosphenes (Ar-P=P-Ar). Significant impact upon lowest energy excited states.

Authors:  Huo-Lei Peng; John L Payton; John D Protasiewicz; M C Simpson
Journal:  J Phys Chem A       Date:  2009-06-25       Impact factor: 2.781

6.  Optical properties of some new azo photoisomerizable bismaleimide derivatives.

Authors:  Anton Airinei; Nicusor Fifere; Mihaela Homocianu; Constantin Gaina; Viorica Gaina; Bogdan C Simionescu
Journal:  Int J Mol Sci       Date:  2011-09-21       Impact factor: 5.923

7.  Imaging conical intersection dynamics during azobenzene photoisomerization by ultrafast X-ray diffraction.

Authors:  Daniel Keefer; Flavia Aleotti; Jérémy R Rouxel; Francesco Segatta; Bing Gu; Artur Nenov; Marco Garavelli; Shaul Mukamel
Journal:  Proc Natl Acad Sci U S A       Date:  2021-01-19       Impact factor: 12.779

8.  Molecular structure and modeling studies of azobenzene derivatives containing maleimide groups.

Authors:  Corneliu Cojocaru; Anton Airinei; Nicusor Fifere
Journal:  Springerplus       Date:  2013-10-31

9.  Fast photodynamics of azobenzene probed by scanning excited-state potential energy surfaces using slow spectroscopy.

Authors:  Eric M M Tan; Saeed Amirjalayer; Szymon Smolarek; Alexander Vdovin; Francesco Zerbetto; Wybren Jan Buma
Journal:  Nat Commun       Date:  2015-01-06       Impact factor: 14.919

10.  Diffractive imaging of a rotational wavepacket in nitrogen molecules with femtosecond megaelectronvolt electron pulses.

Authors:  Jie Yang; Markus Guehr; Theodore Vecchione; Matthew S Robinson; Renkai Li; Nick Hartmann; Xiaozhe Shen; Ryan Coffee; Jeff Corbett; Alan Fry; Kelly Gaffney; Tais Gorkhover; Carsten Hast; Keith Jobe; Igor Makasyuk; Alexander Reid; Joseph Robinson; Sharon Vetter; Fenglin Wang; Stephen Weathersby; Charles Yoneda; Martin Centurion; Xijie Wang
Journal:  Nat Commun       Date:  2016-04-05       Impact factor: 14.919
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