| Literature DB >> 12816416 |
Young Chun Jung1, Rajesh Kumar Mishra, Cheol Hwan Yoon, Kyung Woon Jung.
Abstract
Reported herein is a mild and efficient Pd(II) catalysis, leading to the formation of carbon-carbon bonds between a broad spectrum of organoboron compounds and alkenes. Molecular oxygen was employed to reoxidize the resultant Pd(0) species back to Pd(II) during catalytic cycles. This oxygen protocol promoted the desired Pd(II) catalysis, whereas it retarded competing Pd(0) catalytic pathways such as Heck or Suzuki couplings. [reaction: see text]Entities:
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Year: 2003 PMID: 12816416 DOI: 10.1021/ol034458s
Source DB: PubMed Journal: Org Lett ISSN: 1523-7052 Impact factor: 6.005