| Literature DB >> 12735782 |
Jeffrey D Winkler1, Kevin J Quinn, Colin H MacKinnon, Steven D Hiscock, Emily C McLaughlin.
Abstract
[reaction: see text] A synthesis of 28, the carbon framework of the eleutherobin aglycone, is reported in a 15-step sequence from readily available starting materials. The tandem Diels-Alder reaction of 6 and 7 to produce 18, in which three new rings and six new stereocenters are formed, is a key step in the reaction sequence.Entities:
Mesh：
Substances：
Year: 2003 PMID： 12735782 DOI： 10.1021/ol0345226
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005