Literature DB >> 12711771

Hexa-mu-chloro-mu4-oxo-tetrakis[[5-(2,4,6-trimethylphenyl)pyrazole-kappaN2]copper(II)].

Xiaoming Liu1, Colin A Kilner, Malcolm A Halcrow.   

Abstract

The title compound, [Cu(4)Cl(6)O(C(12)H(14)N(2))(4)], is a new example of the well known [Cu(4)(mu(4)-O)(mu-X)(6)L(4)] class of complex (X(-) is Cl(-), Br(-) or I(-), and L is a monodentate ligand). The molecule has crystallographic C(2) symmetry, with two Cl(-) ions on each edge of a Cu(4) tetrahedron. Two of these, on opposite edges of the tetrahedron, accept intramolecular hydrogen bonds from two of the pyrazole N-H donors.

Entities:  

Year:  2003        PMID: 12711771     DOI: 10.1107/s0108270103002853

Source DB:  PubMed          Journal:  Acta Crystallogr C        ISSN: 0108-2701            Impact factor:   1.172


  1 in total

1.  Hexa-μ(2)-chlorido-μ(4)-oxido-tetra-kis-[(3-methyl-5-phenyl-1H-pyrazole-κN)copper(II)].

Authors:  Hongshan He
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2011-01-08
  1 in total

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