| Literature DB >> 12711771 |
Xiaoming Liu1, Colin A Kilner, Malcolm A Halcrow.
Abstract
The title compound, [Cu(4)Cl(6)O(C(12)H(14)N(2))(4)], is a new example of the well known [Cu(4)(mu(4)-O)(mu-X)(6)L(4)] class of complex (X(-) is Cl(-), Br(-) or I(-), and L is a monodentate ligand). The molecule has crystallographic C(2) symmetry, with two Cl(-) ions on each edge of a Cu(4) tetrahedron. Two of these, on opposite edges of the tetrahedron, accept intramolecular hydrogen bonds from two of the pyrazole N-H donors.Entities:
Year: 2003 PMID: 12711771 DOI: 10.1107/s0108270103002853
Source DB: PubMed Journal: Acta Crystallogr C ISSN: 0108-2701 Impact factor: 1.172