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Literature DB >> 12693203

Supramolecular assembly of trimeric gold(I) pyrazolates through aurophilic attractions.

Abstract

The supramolecular architecture of trinuclear gold(I) pyrazolato aggregates is held together by intermolecular aurophilic attractions, sterically governed by the substituents on the pyrazole rings. A two-dimensional network of [Au(mu-pz)]3 complexes, 1 (pz = pyrazolato anion, C3H3N2-), and a large intricate aggregate of 16 [Au(mu-4-Me-pz)]3 complexes in 2 have been determined crystallographically. Under UV irradiation at ambient temperature, solid samples of 1 and 2 luminesce with lambda max = 626 and 631 cm-1, respectively, attributed to intermolecular Au...Au aurophilic contacts.

Entities: Chemical Species

Year: 2003 PMID： 12693203 DOI： 10.1021/ic026051+

Source DB: PubMed Journal: Inorg Chem ISSN： 0020-1669 Impact factor: 5.165

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Cited

3 in total

1. Tunable trimers: using temperature and pressure to control luminescent emission in gold(I) pyrazolate-based trimers.

Authors: Christopher H Woodall; Sara Fuertes; Christine M Beavers; Lauren E Hatcher; Andrew Parlett; Helena J Shepherd; Jeppe Christensen; Simon J Teat; Mourad Intissar; Alexandre Rodrigue-Witchel; Yan Suffren; Christian Reber; Christopher H Hendon; Davide Tiana; Aron Walsh; Paul R Raithby
Journal: Chemistry Date: 2014-10-21 Impact factor: 5.236

2. A Computational Study of Metallacycles Formed by Pyrazolate Ligands and the Coinage Metals M = Cu(I), Ag(I) and Au(I): (pzM)_n for n = 2, 3, 4, 5 and 6. Comparison with Structures Reported in the Cambridge Crystallographic Data Center (CCDC).

Authors: José Elguero; Ibon Alkorta
Journal: Molecules Date: 2020-11-03 Impact factor: 4.411

3. Interaction between Trinuclear Regium Complexes of Pyrazolate and Anions, a Computational Study.

Authors: Ibon Alkorta; José Elguero; Cristina Trujillo; Goar Sánchez-Sanz
Journal: Int J Mol Sci Date: 2020-10-28 Impact factor: 5.923

3 in total

Supramolecular assembly of trimeric gold(I) pyrazolates through aurophilic attractions.

1. Tunable trimers: using temperature and pressure to control luminescent emission in gold(I) pyrazolate-based trimers.

2. A Computational Study of Metallacycles Formed by Pyrazolate Ligands and the Coinage Metals M = Cu(I), Ag(I) and Au(I): (pzM)n for n = 2, 3, 4, 5 and 6. Comparison with Structures Reported in the Cambridge Crystallographic Data Center (CCDC).

3. Interaction between Trinuclear Regium Complexes of Pyrazolate and Anions, a Computational Study.

2. A Computational Study of Metallacycles Formed by Pyrazolate Ligands and the Coinage Metals M = Cu(I), Ag(I) and Au(I): (pzM)_n for n = 2, 3, 4, 5 and 6. Comparison with Structures Reported in the Cambridge Crystallographic Data Center (CCDC).