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Literature DB >> 12643696

Assembly of resorcinarene capsules in wet solvents.

Abstract

Resorcinarenes assemble in wet chloroform or benzene to form hexameric capsules, resembling inflated cubes or volleyballs. NMR methods are used to determine the number of solvent molecules detained inside; eight molecules of benzene are encapsulated.

Entities: Chemical

Year: 2003 PMID： 12643696 DOI： 10.1021/ja027982n

Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419

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Cited

15 in total

1. Experimental and computational probes of the space in a self-assembled capsule.

Authors: Dariush Ajami; Tetsuo Iwasawa; Julius Rebek
Journal: Proc Natl Acad Sci U S A Date: 2006-06-02 Impact factor: 11.205

2. Molecular recognition and self-assembly special feature: Disproportionation and self-sorting in molecular encapsulation.

Authors: Dariush Ajami; Jun-Li Hou; Trevor J Dale; Elizabeth Barrett; Julius Rebek
Journal: Proc Natl Acad Sci U S A Date: 2009-02-27 Impact factor: 11.205

9. To catalyze or not to catalyze: elucidation of the subtle differences between the hexameric capsules of pyrogallolarene and resorcinarene.

Authors: Qi Zhang; Lorenzo Catti; Ville R I Kaila; Konrad Tiefenbacher
Journal: Chem Sci Date: 2016-11-15 Impact factor: 9.825

10. Optimized iminium-catalysed 1,4-reductions inside the resorcinarene capsule: achieving >90% ee with proline as catalyst.

Authors: Daria Sokolova; Konrad Tiefenbacher
Journal: RSC Adv Date: 2021-07-14 Impact factor: 4.036

Assembly of resorcinarene capsules in wet solvents.

1. Experimental and computational probes of the space in a self-assembled capsule.

2. Molecular recognition and self-assembly special feature: Disproportionation and self-sorting in molecular encapsulation.

3. Resorcinarenes are hexameric capsules in solution.

4. Supramolecular blueprint approach to metal-coordinated capsules.

5. Compressed alkanes in reversible encapsulation complexes.

6. A light controlled cavitand wall regulates guest binding.

7. Supramolecular architecture with a cavitand-capsule chimera.

8. Terpene cyclization catalysed inside a self-assembled cavity.

9. To catalyze or not to catalyze: elucidation of the subtle differences between the hexameric capsules of pyrogallolarene and resorcinarene.

10. Optimized iminium-catalysed 1,4-reductions inside the resorcinarene capsule: achieving >90% ee with proline as catalyst.