| Literature DB >> 12556169 |
Narihiro Toda1, Mayuko Ori, Kazuko Takami, Keiko Tago, Hiroshi Kogen.
Abstract
[reaction: see text] A stereoselective total synthesis of (+)-benzastatin E (1) is described. The synthesis involves a diastereoselective Grignard addition to 2-acylindoline 2, which is derived from commercially available (S)-2-indolinecarboxylic acid (3). The unknown absolute configuration of (+)-1 is determined as (9S,10R).Entities:
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Year: 2003 PMID： 12556169 DOI： 10.1021/ol027215t
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005