Literature DB >> 12467441

Synthesis of new tren-based tris-macrocycles. Anion cluster assembling inside the cavity generated by a bowl-shaped receptor.

Carla Bazzicalupi1, Andrea Bencini, Emanuela Berni, Antonio Bianchi, Samuele Ciattini, Claudia Giorgi, Sauro Maoggi, Piero Paoletti, Barbara Valtancoli.   

Abstract

The synthesis of three new tris-macrocycles, containing three [12]aneN(4) (L1), [12]aneN(3)O (L2), or [14]aneN(4) (L3) moieties appended to a tren unit, is reported. The crystal structure of the [(Na(ClO(4))(6)) subset L1(2)H(13)]Na(6)Cl(2)(ClO(4))(12) compound shows the anionic cluster [Na(ClO(4))(6)](5)(-) assembled inside the cavity defined by two bowl-shaped polyammonium receptors, held by multiple charge-charge and hydrogen bond interactions.

Entities:  

Year:  2002        PMID: 12467441     DOI: 10.1021/jo020474b

Source DB:  PubMed          Journal:  J Org Chem        ISSN: 0022-3263            Impact factor:   4.354


  2 in total

1.  Anion Cluster: Assembly of Dihydrogen Phosphates for the Formation of a Cyclic Anion Octamer.

Authors:  Md Alamgir Hossain; Muhammet Işıklan; Avijit Pramanik; Musabbir A Saeed; Frank R Fronczek
Journal:  Cryst Growth Des       Date:  2012-02-01       Impact factor: 4.076

2.  High-affinity and selective detection of pyrophosphate in water by a resorcinarene salt receptor.

Authors:  Ngong Kodiah Beyeh; Isabel Díez; S Maryamdokht Taimoory; Daniel Meister; Andrew I Feig; John F Trant; Robin H A Ras; Kari Rissanen
Journal:  Chem Sci       Date:  2017-12-19       Impact factor: 9.825

  2 in total

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