| Literature DB >> 22435043 |
Md Alamgir Hossain1, Muhammet Işıklan, Avijit Pramanik, Musabbir A Saeed, Frank R Fronczek.
Abstract
Structural characterization of a dihydrogen phosphate complex of triprotonated tris[2-(2-thienylmethylamino)ethyl] amine shows that eight dihydrogen phosphate anions are assembled around the host by strong interactions of H-bond donors and acceptors to form a new type of cyclic anion octamer as (H(2)PO(4) (-))(8), an analogy of cyclic water octamer. The presence of an anion cluster has also been identified by electrospray ionization mass spectrometry and (31)P NMR experiments.Entities:
Year: 2012 PMID: 22435043 PMCID: PMC3306550 DOI: 10.1021/cg201464k
Source DB: PubMed Journal: Cryst Growth Des ISSN: 1528-7483 Impact factor: 4.076