Literature DB >> 12465921

Highly enantioselective hydrogenation of enol acetates catalyzed by Ru-TunaPhos complexes.

Shulin Wu1, Weimin Wang, Wenjun Tang, Min Lin, Xumu Zhang.   

Abstract

[reaction: see text] The chiral disphosphines with tunable dihedral angles (TunaPhos) have been used for asymmetric hydrogenation of enol acetates and dihedral-angle-dependent enantioselectivities were observed. C2-TunaPhos has been proved to be effective for Ru-catalyzed asymmetric hydrogenation of electron-deficient and other enol acetates.

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Year:  2002        PMID： 12465921     DOI： 10.1021/ol027010k

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  3 in total

1.  Remarkably diastereoselective synthesis of a chiral biphenyl diphosphine ligand and its application in asymmetric hydrogenation.

Authors:  Liqin Qiu; Jing Wu; Shusun Chan; Terry T-L Au-Yeung; Jian-Xin Ji; Rongwei Guo; Cheng-Chao Pai; Zhongyuan Zhou; Xingshu Li; Qing-Hua Fan; Albert S C Chan
Journal:  Proc Natl Acad Sci U S A       Date:  2004-04-05       Impact factor: 11.205

2.  1,1'-Bicyclo-hexyl-1,1'-diyl 1,1'-biphenyl-2,2'-dicarboxyl-ate.

Authors:  Hoong-Kun Fun; Ching Kheng Quah; Dongdong Wu; Yan Zhang
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2012-05-05

3.  A supramolecularly tunable chiral diphosphine ligand: application to Rh and Ir-catalyzed enantioselective hydrogenation.

Authors:  Xi-Chang Zhang; Yi-Hu Hu; Chuan-Fu Chen; Qiang Fang; Li-Yao Yang; Ying-Bo Lu; Lin-Jie Xie; Jing Wu; Shijun Li; Wenjun Fang
Journal:  Chem Sci       Date:  2016-03-31       Impact factor: 9.825
  3 in total

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