Literature DB >> 12415180

9,9-Dimethoxy-7,11-diphenyl-2,4-diazaspiro[5.5]undecane-1,3,5-trione monohydrate.

S M Malathy Sony1, M Kuppayee, M N Ponnuswamy, D Bhasker Reddy, V Padmavathi, Hoong Kun Fun.   

Abstract

Due to steric repulsions, the cyclohexane ring in the title compound, C(23)H(24)N(2)O(5).H(2)O, shows some bond-length abnormalities and adopts a chair conformation. The pyrimidine and cyclohexane rings are approximately perpendicular to each other, and the phenyl rings are equatorial. C-H.pi and N-H.O intermolecular interactions, as well as C-H.O inter- and intramolecular interactions, occur between the molecules. In addition to van der Waals interactions, the water molecule interacts with the pyrimidinetrione ring to stabilize the structure.

Entities:  

Year:  2002        PMID: 12415180     DOI: 10.1107/s0108270102017080

Source DB:  PubMed          Journal:  Acta Crystallogr C        ISSN: 0108-2701            Impact factor:   1.172


  1 in total

1.  1,1',3,3',5,5'-Hexamethyl-spiro-[furo[2,3-d]pyrimidine-6(5H),5'-pyrimidine]-2,2',4,4',6'(1H,3H,1'H,3'H,5'H)-penta-one.

Authors:  Nader Noroozi Pesyan; Saeed Rastgar; Yaser Hosseini
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2009-05-29
  1 in total

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