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Literature DB >> 12240333

A phenoxyl radical complex of copper(II).

L Benisvy¹, A J Blake, D Collison, E S Davies, C D Garner, E J McInnes, J McMaster, G Whittaker, C Wilson.

Abstract

A new N,O-bidentate pro-ligand (HL), [ML2] (M = Cu, Zn) and [CuL2][BF4] have been synthesised; [CuL2].4DMF and [CuL2][BF4].2CH2Cl2 have been crystallographically and spectroscopically characterised; these data indicate that [CuL2]+ cations are constituted as [Cu2+(L.)(L-)]+ and involve the phenoxyl radical L..

Entities: Chemical Gene

Year: 2001 PMID： 12240333 DOI： 10.1039/b105186p

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

7 in total

1. Ligand radical localization in a nonsymmetric one-electron oxidized Ni(II) bis-phenoxide complex.

Authors: Tim Storr; Pratik Verma; Yuichi Shimazaki; Erik C Wasinger; T Daniel P Stack
Journal: Chemistry Date: 2010-08-09 Impact factor: 5.236

2. Detailed evaluation of the geometric and electronic structures of one-electron oxidized group 10 (Ni, Pd, and Pt) metal(II)-(disalicylidene)diamine complexes.

Authors: Yuichi Shimazaki; T Daniel P Stack; Tim Storr
Journal: Inorg Chem Date: 2009-09-07 Impact factor: 5.165

3. Nuclease activity via self-activation and anticancer activity of a mononuclear copper(II) complex: novel role of the tertiary butyl group in the ligand frame.

Authors: Kaushik Ghosh; Pramod Kumar; Varun Mohan; Udai P Singh; Sahba Kasiri; Subhrangsu S Mandal
Journal: Inorg Chem Date: 2012-02-28 Impact factor: 5.165

A phenoxyl radical complex of copper(II).

1. Ligand radical localization in a nonsymmetric one-electron oxidized Ni(II) bis-phenoxide complex.

2. Detailed evaluation of the geometric and electronic structures of one-electron oxidized group 10 (Ni, Pd, and Pt) metal(II)-(disalicylidene)diamine complexes.

3. Nuclease activity via self-activation and anticancer activity of a mononuclear copper(II) complex: novel role of the tertiary butyl group in the ligand frame.

4. Zinc(II) and Nickel(II) Benzoate Complexes from the Use of 1-methyl-4,5-diphenylimidazole.

5. Probing concerted proton-electron transfer in phenol-imidazoles.

6. Defining the electronic and geometric structure of one-electron oxidized copper-bis-phenoxide complexes.

7. Spectroscopic Studies on the Interaction of Metallic Ions with an Imidazolyl-Phenolic System.