| Literature DB >> 12205370 |
Anwar Usman1, Ibrahim Abdul Razak, Suchada Chantrapromma, Hoong Kun Fun, A Sreekanth, S Sivakumar, M R Prathapachandra Kurup.
Abstract
One half of the molecule of the title complex, [Mn(C(14)H(13)N(4)S)(2)], is related to the other half by a twofold axis passing through the Mn atom. This high-spin Mn atom is six-coordinated, in an octahedral geometry, by the azomethine N, the pyridyl N and the thiolate S atom of two planar 1-(pyridin-2-yl)ethanone N(4)-phenylthiosemicarbazone ligands. In the crystal, the molecules are interconnected by N-H.S and C-H.N interactions, forming a three-dimensional network.Entities:
Year: 2002 PMID: 12205370 DOI: 10.1107/S0108270102011976
Source DB: PubMed Journal: Acta Crystallogr C ISSN: 0108-2701 Impact factor: 1.172