| Literature DB >> 12201714 |
Akio Ojida1, Toru Yamano, Naohiro Taya, Akihiro Tasaka.
Abstract
[reaction: see text] Highly enantioselective Reformatsky reaction of ketones was accomplished using cinchona alkaloids as chiral ligands. Chelation with the sp(2)-nitrogen adjacent to the reactive carbonyl center contributed the enantioface discrimination for the high enantioselectivities.Entities:
Mesh：
Substances：
Year: 2002 PMID： 12201714 DOI： 10.1021/ol0263189
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005