Literature DB >> 12116985

Formation of [Ar*Ge(CH2C(Me)C(Me)CH2)CH2C(Me)=]2 (Ar* = C6H3-2,6-Trip2; Trip = C6H2-2,4,6-i-Pr3) via reaction of Ar*GeGeAr* with 2,3-dimethyl-1,3-butadiene: evidence for the existence of a germanium analogue of an alkyne.

Matthias Stender1, Andrew D Phillips, Philip P Power.   

Abstract

The reduction of Ar*GeCl (Ar* = C6H3-2,6-Trip2; Trip = C6H2-2,4,6-i-Pr3) with one equivalent of potassium leads to the formation of a germanium analogue of an alkyne Ar*GeGeAr* 1; reaction of 1 with 2,3-dimethyl-1,3-butadiene yields [Ar*Ge(CH2C(Me)C(Me)CH2)CH2C(Me)=]2 2, which was structurally characterized.

Entities:  

Year:  2002        PMID： 12116985     DOI： 10.1039/b203403d

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  5 in total

1.  Main-group elements as transition metals.

Authors:  Philip P Power
Journal:  Nature       Date:  2010-01-14       Impact factor: 49.962

2.  Is It Possible To Prepare and Stabilize Triple-Bonded Thallium≡Antimony Molecules Using Substituents?

Authors:  Jia-Syun Lu; Ming-Chung Yang; Ming-Der Su
Journal:  ACS Omega       Date:  2018-08-30

3.  A computational study to determine whether substituents make E13[triple bond, length as m-dash]nitrogen (E13 = B, Al, Ga, In, and Tl) triple bonds synthetically accessible.

Authors:  Shi-Lin Zhang; Ming-Chung Yang; Ming-Der Su
Journal:  RSC Adv       Date:  2019-04-17       Impact factor: 4.036

Review 4.  Recent advances of group 14 dimetallenes and dimetallynes in bond activation and catalysis.

Authors:  Franziska Hanusch; Lisa Groll; Shigeyoshi Inoue
Journal:  Chem Sci       Date:  2020-08-03       Impact factor: 9.825

5.  Substituent Effects on the Stability of Thallium and Phosphorus Triple Bonds: A Density Functional Study.

Authors:  Jia-Syun Lu; Ming-Chung Yang; Ming-Der Su
Journal:  Molecules       Date:  2017-07-05       Impact factor: 4.411
  5 in total

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