Literature DB >> 11955001

Uncatalyzed and amine catalyzed decarboxylation of acetoacetic acid: an examination in terms of No Barrier Theory.

J Peter Guthrie1.   

Abstract

Rate constants for decarboxylation of acetoacetic acid, its anion, and its imine with aminoacetonitrile have been calculated from equilibrium constants and distortion energies using No Barrier Theory. The mechanisms of decarboxylation of both acetoacetic acid and its imine involve preequilibrium formation of the zwitterion. Copyright 2002 Elsevier Science (USA).

Entities:  

Mesh：

Substances：

Year:  2002        PMID： 11955001     DOI： 10.1006/bioo.2001.1231

Source DB:  PubMed          Journal:  Bioorg Chem        ISSN： 0045-2068            Impact factor:   5.275


  4 in total

1.  Cloning and characterization of a novel beta-transaminase from Mesorhizobium sp. strain LUK: a new biocatalyst for the synthesis of enantiomerically pure beta-amino acids.

Authors:  Juhan Kim; Dohyun Kyung; Hyungdon Yun; Byung-Kwan Cho; Joo-Hyun Seo; Minho Cha; Byung-Gee Kim
Journal:  Appl Environ Microbiol       Date:  2007-01-26       Impact factor: 4.792

2.  Concert along the Edge: Dynamics and the Nature of the Border between General and Specific Acid-Base Catalysis.

Authors:  Hannah R Aziz; Daniel A Singleton
Journal:  J Am Chem Soc       Date:  2017-04-11       Impact factor: 15.419

3.  Biomarkers of Redox Balance Adjusted to Exercise Intensity as a Useful Tool to Identify Patients at Risk of Muscle Disease through Exercise Test.

Authors:  Pierre-Edouard Grillet; Stéphanie Badiou; Karen Lambert; Thibault Sutra; Maëlle Plawecki; Eric Raynaud de Mauverger; Jean-Frédéric Brun; Jacques Mercier; Fares Gouzi; Jean-Paul Cristol
Journal:  Nutrients       Date:  2022-04-29       Impact factor: 6.706

4.  Curcuminoid biosynthesis by two type III polyketide synthases in the herb Curcuma longa.

Authors:  Yohei Katsuyama; Tomoko Kita; Nobutaka Funa; Sueharu Horinouchi
Journal:  J Biol Chem       Date:  2009-03-03       Impact factor: 5.157
  4 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.