Literature DB >> 11870325

1,3-Dimethyl-2-oxo-4,6-diphenyl-1,2,3,4-tetrahydropyridine-3-carbonitrile.

Urmila H Patel1, Chaitanya G Dave, Mukesh M Jotani, Hetal C Shah.   

Abstract

The crystal structure of the title compound, C(20)H(18)N(2)O, reveals a distorted half-chair conformation of the central tetrahydropyridine (THP) ring, with the cyano- and adjacent phenyl-substituted C atoms displaced by 0.329 (1) and -0.315 (1) A, respectively, from the THP best plane. Steric interactions force the phenyl rings out of the THP plane by 49.21 (9) and 65.76 (5). The cyano moiety is coplanar with the THP plane.

Entities:  

Year:  2002        PMID: 11870325     DOI: 10.1107/s0108270102000185

Source DB:  PubMed          Journal:  Acta Crystallogr C        ISSN: 0108-2701            Impact factor:   1.172


  1 in total

1.  Isotypic crystal structures of 1-benzyl-4-(4-bromo-phen-yl)-2-imino-1,2,5,6,7,8,9,10-octa-hydro-cyclo-octa-[b]pyridine-3-carbo-nitrile and 1-benzyl-4-(4-fluoro-phen-yl)-2-imino-1,2,5,6,7,8,9,10-octa-hydro-cyclo-octa-[b]pyridine-3-carbo-nitrile.

Authors:  R A Nagalakshmi; J Suresh; S Maharani; R Ranjith Kumar; P L Nilantha Lakshman
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2014-10-18
  1 in total

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