Literature DB >> 11828090

1'-Acetylferrocene-1-carboxylic acid: an instance of hydrogen bonding in the rare dimeric acid-to-ketone mode.

Jacob M Newman1, Markos M Papadakis, Hugh W Thompson, Roger A Lalancette.   

Abstract

The title compound, [Fe(C(6)H(5)O(2))(C(7)H(7)O)], adopts a conformation involving partial staggering of its rings and aggregates in the solid as acid-to-ketone hydrogen-bonding dimers [O.O = 2.720(4)A and O-H...O = 164 degree] having centrosymmetrically related components. Close intermolecular C-H...O contacts were found to both carboxyl O atoms.

Entities:  

Year:  2002        PMID: 11828090     DOI: 10.1107/s0108270101021771

Source DB:  PubMed          Journal:  Acta Crystallogr C        ISSN: 0108-2701            Impact factor:   1.172


  1 in total

1.  (±)-2-Oxocyclo-penta-neacetic acid: catemeric hydrogen bonding in a γ-keto acid.

Authors:  Georgia Efthimiopoulos; Markos M Papadakis; Hugh W Thompson; Roger A Lalancette
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2009-03-31
  1 in total

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