| Literature DB >> 11784170 |
Abstract
A new tin recycling method for Stille couplings catalytic in tin is reported. PMHS made hypercoordinate by KF((aq)) allows Me(3)SnH to be efficiently recycled during a Pd(0)-catalyzed hydrostannation/Stille cascade. Relative to previously disclosed protocols, reaction times are shorter and because this process is believed to proceed through a Me(3)SnF intermediate the hazards and problems associated with trimethyltins are also diminished.[reaction: see text]Entities:
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Year: 2001 PMID： 11784170 DOI： 10.1021/ol016792z
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005