Literature DB >> 11538378

Isotopic exchange between carbon dioxide and ozone via O(1D) in the stratosphere.

Y L Yung1, W B DeMore, J P Pinto.   

Abstract

We propose a novel mechanism for isotopic exchange between CO2 and O3 via O(1D) + CO2 --> CO3* followed by CO3* --> CO2 + O(3P). A one-dimensional model calculation shows that this mechanism can account for the enrichment in 18O in the stratospheric CO2 observed by Gamo et al. [1989], using the heavy O3 profile observed by Mauersberger [1981]. The implications of this mechanism for other stratospheric species and as a source of isotopically heavy CO2 in the troposphere are briefly discussed.

Entities:  

Keywords:  NASA Discipline Exobiology; NASA Discipline Number 52-20; NASA Program Exobiology; Non-NASA Center

Mesh：

Substances：

Year:  1991        PMID： 11538378     DOI： 10.1029/90gl02478

Source DB:  PubMed          Journal:  Geophys Res Lett        ISSN： 0094-8276            Impact factor:   4.720


  8 in total

1.  The role of symmetry in the mass independent isotope effect in ozone.

Authors:  Greg Michalski; S K Bhattacharya
Journal:  Proc Natl Acad Sci U S A       Date:  2009-03-23       Impact factor: 11.205

2.  Introduction to chemistry and applications in nature of mass independent isotope effects special feature.

Authors:  Mark H Thiemens
Journal:  Proc Natl Acad Sci U S A       Date:  2013-10-28       Impact factor: 11.205

3.  Oxygen isotopic composition of carbon dioxide in the middle atmosphere.

Authors:  Mao-Chang Liang; Geoffrey A Blake; Brenton R Lewis; Yuk L Yung
Journal:  Proc Natl Acad Sci U S A       Date:  2006-12-26       Impact factor: 11.205

4.  An analytical formulation of isotope fractionation due to self-shielding.

Authors:  J R Lyons
Journal:  Geochim Cosmochim Acta       Date:  2020-05-12       Impact factor: 5.010

5.  Oxygen isotope anomaly in tropospheric CO2 and implications for CO2 residence time in the atmosphere and gross primary productivity.

Authors:  Mao-Chang Liang; Sasadhar Mahata; Amzad H Laskar; Mark H Thiemens; Sally Newman
Journal:  Sci Rep       Date:  2017-10-13       Impact factor: 4.379

6.  Global 3-D Simulations of the Triple Oxygen Isotope Signature Δ17O in Atmospheric CO2.

Authors:  Gerbrand Koren; Linda Schneider; Ivar R van der Velde; Erik van Schaik; Sergey S Gromov; Getachew A Adnew; Dorota J Mrozek Martino; Magdalena E G Hofmann; Mao-Chang Liang; Sasadhar Mahata; Peter Bergamaschi; Ingrid T van der Laan-Luijkx; Maarten C Krol; Thomas Röckmann; Wouter Peters
Journal:  J Geophys Res Atmos       Date:  2019-08-04       Impact factor: 4.261

7.  Determination of the triple oxygen and carbon isotopic composition of CO2 from atomic ion fragments formed in the ion source of the 253 Ultra high-resolution isotope ratio mass spectrometer.

Authors:  Getachew A Adnew; Magdalena E G Hofmann; Dipayan Paul; Amzad Laskar; Jakub Surma; Nina Albrecht; Andreas Pack; Johannes Schwieters; Gerbrand Koren; Wouter Peters; Thomas Röckmann
Journal:  Rapid Commun Mass Spectrom       Date:  2019-09-15       Impact factor: 2.419

8.  Triple oxygen isotope evidence for limited mid-Proterozoic primary productivity.

Authors:  Peter W Crockford; Justin A Hayles; Huiming Bao; Noah J Planavsky; Andrey Bekker; Philip W Fralick; Galen P Halverson; Thi Hao Bui; Yongbo Peng; Boswell A Wing
Journal:  Nature       Date:  2018-07-18       Impact factor: 49.962
  8 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.