Literature DB >> 11538264

Is interstellar detection of higher members of the linear radicals CnCH and CnN feasible?

F Pauzat1, Y Ellinger, A D McLean.   

Abstract

Rotational constants and dipole moments for linear-chain radicals CnCH and CnN are estimated using a combination of ab initio molecular orbital calculations and observed data on the starting members of the series. CnCH with n = 0-5 have been observed by radioastronomy in carbon-rich interstellar clouds; higher members of the series have 2 pi ground states with large dipole moments and are strong candidates for observation. CN and C3N have also been observed by radioastronomy; higher members of the series, with the possible exception of C5N, have 2 pi ground states with near-zero dipole moments making their interstellar detection hopeless under present observational conditions. C5N can be a strong candidate only if it has a 2 sigma ground state, and our best computations so far indicate that this is not the case.

Entities:  

Keywords:  NASA Discipline Exobiology; NASA Discipline Number 52-10; NASA Program Exobiology; Non-NASA Center

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Year:  1991        PMID: 11538264     DOI: 10.1086/185948

Source DB:  PubMed          Journal:  Astrophys J        ISSN: 0004-637X            Impact factor:   5.874


  1 in total

1.  Interstellar nitrile anions: Detection of C3N- and C5N- in TMC-1.

Authors:  J Cernicharo; N Marcelino; J R Pardo; M Agúndez; B Tercero; P de Vicente; C Cabezas; C Bermúdez
Journal:  Astron Astrophys       Date:  2020-09-23       Impact factor: 5.802

  1 in total

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