| Literature DB >> 11430022 |
C Atienza1, C Mateo, O de Frutos, A M Echavarren.
Abstract
[figure: see text] Thermal cyclization of 1-[2-(trimethylsilylethynyl)phenyl]-3-arylpropinones was expected to give benzo[b]fluorenones. However, benzo[a]-fluorenones were also formed as a result of a new rearrangement. These tetracycles possess the core structure of the fluostatins and isoprekinamycin.Entities:
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Year: 2001 PMID： 11430022 DOI： 10.1021/ol0067336
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005