Literature DB >> 11173422

3,3-Diphenyl-6-(p-toluenesulfonyl)-6-aza-3-silabicyclo[3.1.0]hexane.

J L Matthews 1, D R McArthur , K W Muir , D N White .   

Abstract

The title compound, C23H23NO2SSi, at 100 K adopts a boat conformation which brings the C-H bond of an axial phenyl substituent into proximity [C...N = 3.376 (1) A] with the aziridine lone pair. The factors which favour this conformation for bicyclo[3.1.0]hexane systems are considered.

Entities:  

Year:  2001        PMID: 11173422     DOI: 10.1107/s0108270100015638

Source DB:  PubMed          Journal:  Acta Crystallogr C        ISSN: 0108-2701            Impact factor:   1.172


  1 in total

1.  2-Di-chloro-methyl-N-ethyl-5-(1-phenyl-silolan-1-yl)cyclo-pent-3-enecarboxamide.

Authors:  Han Xiao; Wan-Qiu Yang; Liang Shen
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2013-09-12
  1 in total

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