Literature DB >> 11088208

Universal and nonuniversal features of glassy relaxation in propylene carbonate

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Abstract

It is demonstrated that the susceptibility spectra of supercooled propylene carbonate as measured by depolarized-light scattering, dielectric-loss, and incoherent quasielastic neutron-scattering spectroscopy within the GHz window are simultaneously described by the solutions of a two-component schematic model of the mode-coupling theory (MCT) for the evolution of glassy dynamics. It is shown that the universal beta-relaxation-scaling laws, dealing with the asymptotic behavior of the MCT solutions, describe the qualitative features of the calculated spectra. But the nonuniversal corrections to the scaling laws render it impossible to achieve a complete quantitative description using only the leading-order-asymptotic results.

Entities:  

Year:  2000        PMID: 11088208     DOI: 10.1103/physreve.61.4133

Source DB:  PubMed          Journal:  Phys Rev E Stat Phys Plasmas Fluids Relat Interdiscip Topics        ISSN: 1063-651X


  5 in total

1.  Viscoelastic dynamics of polymer thin films and surfaces.

Authors:  S Herminghaus; K Jacobs; R Seemann
Journal:  Eur Phys J E Soft Matter       Date:  2003-09       Impact factor: 1.890

2.  Excess wing in glass-forming glycerol and LiCl-glycerol mixtures detected by neutron scattering.

Authors:  S Gupta; N Arend; P Lunkenheimer; A Loidl; L Stingaciu; N Jalarvo; E Mamontov; M Ohl
Journal:  Eur Phys J E Soft Matter       Date:  2015-01-22       Impact factor: 1.890

3.  Simulated glass-forming polymer melts: dynamic scattering functions, chain length effects, and mode-coupling theory analysis.

Authors:  S Frey; F Weysser; H Meyer; J Farago; M Fuchs; J Baschnagel
Journal:  Eur Phys J E Soft Matter       Date:  2015-02-26       Impact factor: 1.890

4.  Characteristic length scales of the secondary relaxations in glass-forming glycerol.

Authors:  S Gupta; E Mamontov; N Jalarvo; L Stingaciu; M Ohl
Journal:  Eur Phys J E Soft Matter       Date:  2016-03-29       Impact factor: 1.890

5.  MD simulation of concentrated polymer solutions: structural relaxation near the glass transition.

Authors:  S Peter; H Meyer; J Baschnagel
Journal:  Eur Phys J E Soft Matter       Date:  2009-02       Impact factor: 1.890

  5 in total

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