Literature DB >> 25612850

Excess wing in glass-forming glycerol and LiCl-glycerol mixtures detected by neutron scattering.

S Gupta1, N Arend, P Lunkenheimer, A Loidl, L Stingaciu, N Jalarvo, E Mamontov, M Ohl.   

Abstract

The relaxational dynamics in glass-forming glycerol and glycerol mixed with LiCl is investigated using different neutron scattering techniques. The performed neutron spin echo experiments, which extend up to relatively long relaxation time scales of the order of 10 ns, should allow for the detection of contributions from the so-called excess wing. This phenomenon, whose microscopic origin is controversially discussed, arises in a variety of glass formers and, until now, was almost exclusively investigated by dielectric spectroscopy and light scattering. Here we show that the relaxational process causing the excess wing can also be detected by neutron scattering, which directly couples to density fluctuations.

Entities:  

Year:  2015        PMID: 25612850     DOI: 10.1140/epje/i2015-15001-0

Source DB:  PubMed          Journal:  Eur Phys J E Soft Matter        ISSN: 1292-8941            Impact factor:   1.890


  29 in total

1.  Spatially heterogeneous dynamics in supercooled liquids.

Authors:  M D Ediger
Journal:  Annu Rev Phys Chem       Date:  2000       Impact factor: 12.703

2.  Broadband dielectric spectroscopy on glass-forming propylene carbonate.

Authors:  U Schneider; P Lunkenheimer; R Brand; A Loidl
Journal:  Phys Rev E Stat Phys Plasmas Fluids Relat Interdiscip Topics       Date:  1999-06

3.  Beta relaxation versus high frequency wing in the dielectric spectra of a binary molecular glass former.

Authors:  T Blochowicz; E A Rössler
Journal:  Phys Rev Lett       Date:  2004-06-04       Impact factor: 9.161

4.  Glassy relaxation and excess wing in mode-coupling theory: the dynamic susceptibility of propylene carbonate above and below T(c).

Authors:  Markus Domschke; Mie Marsilius; Thomas Blochowicz; Thomas Voigtmann
Journal:  Phys Rev E Stat Nonlin Soft Matter Phys       Date:  2011-09-30

5.  Anelastic to plastic transition in metallic glass-forming liquids.

Authors:  John S Harmon; Marios D Demetriou; William L Johnson; Konrad Samwer
Journal:  Phys Rev Lett       Date:  2007-09-28       Impact factor: 9.161

6.  Specific-heat spectroscopy of glycerol and propylene glycol near the glass transition.

Authors: 
Journal:  Phys Rev B Condens Matter       Date:  1986-08-01

7.  Light-scattering investigation of alpha and beta relaxation near the liquid-glass transition of the molecular glass Salol.

Authors: 
Journal:  Phys Rev A       Date:  1992-09-15       Impact factor: 3.140

8.  A time-of-flight backscattering spectrometer at the Spallation Neutron Source, BASIS.

Authors:  E Mamontov; K W Herwig
Journal:  Rev Sci Instrum       Date:  2011-08       Impact factor: 1.523

9.  Evolution of the dynamic susceptibility in molecular glass formers: results from light scattering, dielectric spectroscopy, and NMR.

Authors:  N Petzold; B Schmidtke; R Kahlau; D Bock; R Meier; B Micko; D Kruk; E A Rössler
Journal:  J Chem Phys       Date:  2013-03-28       Impact factor: 3.488

10.  Debye relaxation and 250 K anomaly in glass forming monohydroxy alcohols.

Authors:  S Bauer; K Burlafinger; C Gainaru; P Lunkenheimer; W Hiller; A Loidl; R Böhmer
Journal:  J Chem Phys       Date:  2013-03-07       Impact factor: 3.488

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  2 in total

1.  Characteristic length scales of the secondary relaxations in glass-forming glycerol.

Authors:  S Gupta; E Mamontov; N Jalarvo; L Stingaciu; M Ohl
Journal:  Eur Phys J E Soft Matter       Date:  2016-03-29       Impact factor: 1.890

2.  Effect of adding nanometre-sized heterogeneities on the structural dynamics and the excess wing of a molecular glass former.

Authors:  S Gupta; J K H Fischer; P Lunkenheimer; A Loidl; E Novak; N Jalarvo; M Ohl
Journal:  Sci Rep       Date:  2016-10-11       Impact factor: 4.379

  2 in total

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