Literature DB >> 11077296

Tris(2-methylphenyl)phosphonium tetrachloroborate.

J M Burke1, J A Howard, T B Marder, C Wilson.   

Abstract

The title compound, C(21)H(22)P(+).BCl(4)(-), is the first structurally characterized example of the [HP(o-tolyl)(3)](+) cation, presented here with BCl(4)(-) as the counter-ion. The cation has a near-tetrahedral P atom and the BCl(4)(-) anion is near-tetrahedral at boron. There are no unusually short cation-anion contacts.

Entities:  

Year:  2000        PMID: 11077296     DOI: 10.1107/s0108270100010623

Source DB:  PubMed          Journal:  Acta Crystallogr C        ISSN: 0108-2701            Impact factor:   1.172


  2 in total

1.  Hexahalodiborate Dianions: A New Family of Binary Boron Halides.

Authors:  Guillaume Bélanger-Chabot; Holger Braunschweig
Journal:  Angew Chem Int Ed Engl       Date:  2019-08-23       Impact factor: 15.336

2.  Crystal structure of (n-but-yl)[2-(2,6-di-meth-oxy-phen-yl)-6-methyl-phen-yl](2-meth-oxy-phen-yl)phospho-nium chloride monohydrate.

Authors:  Ge Feng; Alexander S Filatov; Richard F Jordan
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2016-01-13
  2 in total

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