Literature DB >> 10986505

3,5-Pyrazoledicarboxylic acid monohydrate

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Abstract

In the title compound, C(5)H(4)N(2)O(4).H(2)O, the 3, 5-pyrazoledicarboxylic acid (H(3)pdc) molecules are joined into one-dimensional chains by O-H.O and N-H.O hydrogen bonds, with distances of 2.671 (2) and 2.776 (2) A, respectively. The one-dimensional chains form a three-dimensional structure via O-H.OW and OW-HW.N hydrogen bonds, with distances of 2.597 (3) and 2.780 (3) A, respectively. In addition to the potential for forming open-channel frameworks, access to the six coordination atoms of H(3)pdc can be directly controlled by varying the pH of the reaction environment, allowing further control over the design and synthesis of novel coordination polymers using various metal centers.

Entities:  

Year:  2000        PMID: 10986505     DOI: 10.1107/s0108270100007484

Source DB:  PubMed          Journal:  Acta Crystallogr C        ISSN: 0108-2701            Impact factor:   1.172


  2 in total

1.  Synthesis and structural characterization of 1- and 2-substituted indazoles: ester and carboxylic acid derivatives.

Authors:  Fátima C Teixeira; Hélène Ramos; Inês F Antunes; M João M Curto; M Teresa Duarte; Isabel Bento
Journal:  Molecules       Date:  2006-11-14       Impact factor: 4.411

2.  catena-Poly[[di-aqua-bis-(μ3-5-carboxyl-ato-1H-pyrazole-3-carb-oxy-lic acid-κ(3) O (3):O (3);O (5))dilithium(I)] monohydrate].

Authors:  Wojciech Starosta; Janusz Leciejewicz
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2013-10-12
  2 in total

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