| Literature DB >> 10959858 |
E Marcantoni1, M Massaccesi, M Petrini, G Bartoli, M C Bellucci, M Bosco, L Sambri.
Abstract
The synthetic potentialities of cerium(III) chloride are demonstrated by the synthesis of a nine-membered ring heterocycle component of Griseoviridin (3) in optically active form. The key step involves the stereospecific formation of the alpha-carbalkoxy alkenyl sulfide moiety using a combination system of cerium(III) chloride heptahydrate and sodium iodide.Entities:
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Year: 2000 PMID: 10959858 DOI: 10.1021/jo000116d
Source DB: PubMed Journal: J Org Chem ISSN: 0022-3263 Impact factor: 4.354