Literature DB >> 10956528

Practical ruthenium/lipase-catalyzed asymmetric transformations of ketones and enol acetates to chiral acetates.

H M Jung1, J H Koh, M J Kim, J Park.   

Abstract

Ketones were asymmetrically transformed to chiral acetates by one-pot processes using a lipase and an achiral ruthenium complex under 1 atm of hydrogen gas in ethyl acetate. Molecular hydrogen was also effective for the transformation of enol acetates to chiral acetates without additional acyl donors with the same catalyst system.

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Year:  2000        PMID: 10956528     DOI: 10.1021/ol006169z

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  2 in total

1.  Chemoenzymatic Dynamic Kinetic Asymmetric Transformations of β-Hydroxyketones.

Authors:  Simon Hilker; Daniels Posevins; C Rikard Unelius; Jan-E Bäckvall
Journal:  Chemistry       Date:  2021-10-05       Impact factor: 5.020

2.  A supraparticle-based biomimetic cascade catalyst for continuous flow reaction.

Authors:  Xiaomiao Guo; Nan Xue; Ming Zhang; Rammile Ettelaie; Hengquan Yang
Journal:  Nat Commun       Date:  2022-10-08       Impact factor: 17.694

  2 in total

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