Literature DB >> 10857054

The ascent of parity-violation: exochirality in the solar system and beyond

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Abstract

We review recent developments stemming from Stephen Mason's work on the origin of homochirality, focusing in particular on the parity-violating energy difference (PVED) between enantiomers. We summarize results of calculations of the PVED--both our own and those of other groups--which show that the natural enantiomers are indeed favoured by the weak force in most cases. The PVED has become important not only to explain the selection of the L-amino acids in the origin of life, but also as a "molecular footprint" of fundamental physics, leading to proposals to derive values of the Weinberg angle from future spectroscopic measurements of the PVED. The new field of exochirality--chirality outside the Earth--is now taking off, with reports of excesses of L-amino acids in meteorites, and proposals to look for homochirality as a signature of life on other planets and even in other solar systems. If it was indeed the PVED that determined life's handedness, we would expect to find L-amino acids rather than D everywhere in the universe.

Entities:  

Year:  2000        PMID: 10857054

Source DB:  PubMed          Journal:  Enantiomer        ISSN: 1024-2430


  3 in total

1.  Symmetry breaking by spontaneous crystallization--is it the most plausible source of terrestrial handedness we have long been looking for?--A reappraisal.

Authors:  Martin Avalos; Reyes Babiano; Pedro Cintas; Jose L Jimenez; Juan C Palacios
Journal:  Orig Life Evol Biosph       Date:  2004-08       Impact factor: 1.950

2.  Evaluation of coupled perturbed and density functional methods of computing the parity-violating energy difference between enantiomers.

Authors:  A J MacDermott; G O Hyde; A J Cohen
Journal:  Orig Life Evol Biosph       Date:  2009-03-17       Impact factor: 1.950

3.  Electroweak parity-violating energy shifts of amino acids: the "conformation problem".

Authors:  A J MacDermott; T Fu; G O Hyde; R Nakatsuka; A P Coleman
Journal:  Orig Life Evol Biosph       Date:  2009-03-17       Impact factor: 1.950

  3 in total

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