Literature DB >> 10602206

Catalytic, Regiospecific End-Functionalization of Alkanes: Rhenium-Catalyzed Borylation under Photochemical Conditions.

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Abstract

Approaching a Holy Grail? A regioselective functionalization of alkanes occurs with commercially available rhenium catalysts and borane reagents under photochemical conditions [Eq. (1)]. Mechanistic studies indicate that the regioselectivity results from a direct thermal reaction of a photochemically generated 16-electron boryl complex with alkane.

Entities:  

Year:  1999        PMID： 10602206     DOI： 10.1002/(sici)1521-3773(19991115)38:22<3391::aid-anie3391>3.0.co;2-n

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  15 in total

Review 1.  Nickel-catalyzed cross-couplings involving carbon-oxygen bonds.

Authors:  Brad M Rosen; Kyle W Quasdorf; Daniella A Wilson; Na Zhang; Ana-Maria Resmerita; Neil K Garg; Virgil Percec
Journal:  Chem Rev       Date:  2010-12-06       Impact factor: 60.622

2.  Palladium-catalyzed borylation of primary alkyl bromides.

Authors:  Amruta Joshi-Pangu; Xinghua Ma; Mohamed Diane; Sidra Iqbal; Robert J Kribs; Richard Huang; Chao-Yuan Wang; Mark R Biscoe
Journal:  J Org Chem       Date:  2012-07-23       Impact factor: 4.354

3.  A method for the deprotection of alkylpinacolyl boronate esters.

Authors:  Jing Sun; Michael T Perfetti; Webster L Santos
Journal:  J Org Chem       Date:  2011-04-07       Impact factor: 4.354

Review 4.  Inorganometallics (Transition Metal-Metalloid Complexes) and Catalysis.

Authors:  Bogdan Marciniec; Cezary Pietraszuk; Piotr Pawluć; Hieronim Maciejewski
Journal:  Chem Rev       Date:  2021-12-30       Impact factor: 60.622

5.  Ligand-Promoted Borylation of C(sp(3))-H Bonds with Palladium(II) Catalysts.

Authors:  Jian He; Heng Jiang; Ryosuke Takise; Ru-Yi Zhu; Gang Chen; Hui-Xiong Dai; T G Murali Dhar; Jun Shi; Hao Zhang; Peter T W Cheng; Jin-Quan Yu
Journal:  Angew Chem Int Ed Engl       Date:  2015-11-27       Impact factor: 15.336

6.  Synthesis and structures of anionic rhenium polyhydride complexes of boron-hydride ligands and their application in catalysis.

Authors:  Liam J Donnelly; Simon Parsons; Carole A Morrison; Stephen P Thomas; Jason B Love
Journal:  Chem Sci       Date:  2020-09-09       Impact factor: 9.825

7.  Evolution of C-H Bond Functionalization from Methane to Methodology.

Authors:  John F Hartwig
Journal:  J Am Chem Soc       Date:  2015-12-15       Impact factor: 15.419

Review 8.  Development of Chiral Ligands for the Transition-Metal-Catalyzed Enantioselective Silylation and Borylation of C-H Bonds.

Authors:  Bo Su; John F Hartwig
Journal:  Angew Chem Int Ed Engl       Date:  2021-12-21       Impact factor: 16.823

9.  Mechanism, reactivity, and selectivity of the iridium-catalyzed C(sp3)-H borylation of chlorosilanes.

Authors:  Genping Huang; Marcin Kalek; Rong-Zhen Liao; Fahmi Himo
Journal:  Chem Sci       Date:  2014-12-04       Impact factor: 9.825

Review 10.  Challenges and opportunities for alkane functionalisation using molecular catalysts.

Authors:  Xinxin Tang; Xiangqing Jia; Zheng Huang
Journal:  Chem Sci       Date:  2017-11-09       Impact factor: 9.825
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