Literature DB >> 9722498

Identification and total synthesis of novel fatty acids from the Caribbean sponge Calyx podatypa.

N M Carballeira1, M Pagán, A D Rodríguez.   

Abstract

The phospholipid fatty acid composition of the Caribbean sponge Calyx podatypa was studied, and 85 different fatty acids were identified, in particular the 11-methylpentadecanoic acid and 10-tricosenoic acid, which have no literature precedence. Structural characterization was accomplished by means of gas chromatography-mass spectrometry on their corresponding methyl esters and dimethyl disulfide derivatives. The structure of 11-methylpentadecanoic acid was further confirmed by total synthesis (17% overall yield) starting from commercially available 10-hydroxydecanoic acid.

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Year:  1998        PMID： 9722498     DOI： 10.1021/np9801413

Source DB:  PubMed          Journal:  J Nat Prod        ISSN： 0163-3864            Impact factor:   4.050


  6 in total

1.  Unusual minor nonmethylene-interrupted di-, tri-, and tetraenoic fatty acids in limpet gonads.

Authors:  Hideki Kawashima
Journal:  Lipids       Date:  2005-06       Impact factor: 1.880

2.  Unusual fatty acids in the fat body of the early nesting bumblebee, Bombus pratorum.

Authors:  Josef Cvacka; Edita Kofronová; Sona Vasícková; Karel Stránský; Pavel Jiros; Oldrich Hovorka; Jirí Kindl; Irena Valterová
Journal:  Lipids       Date:  2008-03-26       Impact factor: 1.880

3.  Antineoplastic unsaturated fatty acids from Fijian macroalgae.

Authors:  Ren-Wang Jiang; Mark E Hay; Craig R Fairchild; Jacques Prudhomme; Karine Le Roch; William Aalbersberg; Julia Kubanek
Journal:  Phytochemistry       Date:  2008-08-29       Impact factor: 4.072

4.  First total synthesis and antiprotozoal activity of (Z)-17-methyl-13-octadecenoic acid, a new marine fatty acid from the sponge Polymastia penicillus.

Authors:  Néstor M Carballeira; Nashbly Montano; Rafael Balaña-Fouce; Christopher Fernández Prada
Journal:  Chem Phys Lipids       Date:  2009-06-13       Impact factor: 3.329

5.  Fatty acids in liver, muscle and gonad of three tropical rays including non-methylene-interrupted dienoic fatty acids.

Authors:  Mohamed Vall Ould El Kebir; Gilles Barnathan; Emile M Gaydou; Yves Siau; Joseph Miralles
Journal:  Lipids       Date:  2007-04-03       Impact factor: 1.646

Review 6.  Marine unsaturated fatty acids: structures, bioactivities, biosynthesis and benefits.

Authors:  Yingfang Lu; Yinning Chen; Yulin Wu; Huili Hao; Wenjing Liang; Jun Liu; Riming Huang
Journal:  RSC Adv       Date:  2019-10-31       Impact factor: 4.036
  6 in total

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