Literature DB >> 9383477

Win some, lose some: enthalpy-entropy compensation in weak intermolecular interactions.

J D Dunitz1.   

Abstract

Enthalpy-entropy compensation is a general feature of many chemical reactions and processes in biological systems, but its origin has remained obscure. A simple thermodynamic argument suggests that enthalpy-entropy compensation is a general property of weak intermolecular interactions, and that the two contributions to the free energy should nearly balance out for a hydrogen bond at 300 K.

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Year:  1995        PMID： 9383477     DOI： 10.1016/1074-5521(95)90097-7

Source DB:  PubMed          Journal:  Chem Biol        ISSN： 1074-5521


  119 in total

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9.  The paradoxical thermodynamic basis for the interaction of ethylene glycol, glycine, and sarcosine chains with bovine carbonic anhydrase II: an unexpected manifestation of enthalpy/entropy compensation.

Authors:  Vijay M Krishnamurthy; Brooks R Bohall; Vincent Semetey; George M Whitesides
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10.  Electrostatically optimized Ras-binding Ral guanine dissociation stimulator mutants increase the rate of association by stabilizing the encounter complex.

Authors:  C Kiel; T Selzer; Y Shaul; G Schreiber; C Herrmann
Journal:  Proc Natl Acad Sci U S A       Date:  2004-06-14       Impact factor: 11.205
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