| Literature DB >> 8962050 |
T L Hill1.
Abstract
An exact treatment of adsorption from a one-dimensional lattice gas is used to eliminate and correct a well-known inconsistency in the Brunauer-Emmett-Teller (B.E.T.) equation-namely, Gibbs excess adsorption is not taken into account and the Gibbs integral diverges at the transition point. However, neither model should be considered realistic for experimental adsorption systems.Mesh：
Substances：
Year: 1996 PMID： 8962050 PMCID： PMC26131 DOI： 10.1073/pnas.93.25.14328
Source DB: PubMed Journal: Proc Natl Acad Sci U S A ISSN： 0027-8424 Impact factor: 11.205