Literature DB >> 8953027

Copper-Catalyzed Oxidation of Alcohols to Aldehydes and Ketones: An Efficient, Aerobic Alternative

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Abstract

An efficient, copper-based catalyst has been discovered that oxidizes a wide range of alcohols into aldehydes and ketones under mild conditions. This catalytic system utilizes oxygen or air as the ultimate, stoichiometric oxidant, producing water as the only by-product.

Entities:  

Year:  1996        PMID： 8953027     DOI： 10.1126/science.274.5295.2044

Source DB:  PubMed          Journal:  Science        ISSN： 0036-8075            Impact factor:   47.728


  16 in total

Review 1.  Aerobic copper-catalyzed organic reactions.

Authors:  Scott E Allen; Ryan R Walvoord; Rosaura Padilla-Salinas; Marisa C Kozlowski
Journal:  Chem Rev       Date:  2013-06-20       Impact factor: 60.622

2.  Catalytic Aerobic Oxidation of Alcohols by Copper Complexes Bearing Redox-Active Ligands with Tunable H-Bonding Groups.

Authors:  Khashayar Rajabimoghadam; Yousef Darwish; Umyeena Bashir; Dylan Pitman; Sidney Eichelberger; Maxime A Siegler; Marcel Swart; Isaac Garcia-Bosch
Journal:  J Am Chem Soc       Date:  2018-11-19       Impact factor: 15.419

Review 3.  Copper-Promoted Functionalization of Organic Molecules: from Biologically Relevant Cu/O2 Model Systems to Organometallic Transformations.

Authors:  Rachel Trammell; Khashayar Rajabimoghadam; Isaac Garcia-Bosch
Journal:  Chem Rev       Date:  2019-01-30       Impact factor: 60.622

4.  Highly practical copper(I)/TEMPO catalyst system for chemoselective aerobic oxidation of primary alcohols.

Authors:  Jessica M Hoover; Shannon S Stahl
Journal:  J Am Chem Soc       Date:  2011-10-03       Impact factor: 15.419

5.  Highly efficient Cu(I)-catalyzed oxidation of alcohols to ketones and aldehydes with diaziridinone.

Authors:  Yingguang Zhu; Baoguo Zhao; Yian Shi
Journal:  Org Lett       Date:  2013-02-15       Impact factor: 6.005

6.  Development and comparison of the substrate scope of Pd-catalysts for the aerobic oxidation of alcohols.

Authors:  Mitchell J Schultz; Steven S Hamilton; David R Jensen; Matthew S Sigman
Journal:  J Org Chem       Date:  2005-04-29       Impact factor: 4.354

7.  Copper(I)/TEMPO-catalyzed aerobic oxidation of primary alcohols to aldehydes with ambient air.

Authors:  Jessica M Hoover; Janelle E Steves; Shannon S Stahl
Journal:  Nat Protoc       Date:  2012-05-24       Impact factor: 13.491

Review 8.  Homogeneity of Supported Single-Atom Active Sites Boosting the Selective Catalytic Transformations.

Authors:  Yujie Shi; Yuwei Zhou; Yang Lou; Zupeng Chen; Haifeng Xiong; Yongfa Zhu
Journal:  Adv Sci (Weinh)       Date:  2022-07-09       Impact factor: 17.521

9.  CuCl-catalyzed aerobic oxidation of 2,3-allenols to 1,2-allenic ketones with 1:1 combination of phenanthroline and bipyridine as ligands.

Authors:  Shuxu Gao; Yu Liu; Shengming Ma
Journal:  Beilstein J Org Chem       Date:  2011-04-07       Impact factor: 2.883

10.  Hypervalent iodine(III)-induced methylene acetoxylation of 3-oxo-N-substituted butanamides.

Authors:  Wei-Bing Liu; Cui Chen; Qing Zhang; Zhi-Bo Zhu
Journal:  Beilstein J Org Chem       Date:  2011-10-19       Impact factor: 2.883
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