Literature DB >> 8786368

A two-step efficient chemoenzymatic synthesis of flavonoid glycoside malonates.

S Riva1, B Danieli, M Luisetti.   

Abstract

A simple and high-yielding protocol for the malonylation of some flavonoid glycosides is described. The two-step synthesis is based on the regioselective enzymatic introduction of a benzylmalonyl group by catalysis with the lipase from Candida antarctica, followed by Pd/C hydrogenolysis of the benzyl moiety.

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Year:  1996        PMID: 8786368     DOI: 10.1021/np960239m

Source DB:  PubMed          Journal:  J Nat Prod        ISSN: 0163-3864            Impact factor:   4.050


  3 in total

Review 1.  Enzymatic synthesis of bioactive compounds with high potential for cosmeceutical application.

Authors:  Io Antonopoulou; Simona Varriale; Evangelos Topakas; Ulrika Rova; Paul Christakopoulos; Vincenza Faraco
Journal:  Appl Microbiol Biotechnol       Date:  2016-06-08       Impact factor: 4.813

2.  Synthesis and biological activity of trans-tiliroside derivatives as potent anti-diabetic agents.

Authors:  Yujin Zhu; Yanjun Zhang; Yi Liu; Hongwan Chu; Hongquan Duan
Journal:  Molecules       Date:  2010-12-10       Impact factor: 4.411

Review 3.  Dicarboxylic esters: Useful tools for the biocatalyzed synthesis of hybrid compounds and polymers.

Authors:  Ivan Bassanini; Karl Hult; Sergio Riva
Journal:  Beilstein J Org Chem       Date:  2015-09-09       Impact factor: 2.883

  3 in total

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