Warning: Undefined array key "mm" in /www/wwwroot/www.ai-bt.com/si.php on line 10 Deprecated: trim(): Passing null to parameter #1 ($string) of type string is deprecated in /www/wwwroot/www.ai-bt.com/si.php on line 10 Molecular stereochemistry of [FeIII(TPP)(OCOCF3)].

Literature DB >> 8527097

Molecular stereochemistry of [FeIII(TPP)(OCOCF3)].

Abstract

(meso-Tetraphenylporphinato)(trifluoroacetato)iron(III), [Fe(C2F3O2)(C44H28N4)], consists of a central Fe atom equatorially coordinated to four pyrrole N atoms and axially coordinated th an O atom of the trifluoroacetate group. The average Fe--N bond distance is 2.054(5)A and the Fe atom is displaced 0.483 (1) A from the porphinato plane. The Fe--O distance is 1.921 (4) A. The out-of-plane displacement and the Fe--N bond lengths indicate that the Fe atom is in a high-spin state.

Entities: Chemical Disease

Mesh：

Substances：

Year: 1995 PMID： 8527097 DOI： 10.1107/s010827019401334x

Source DB: PubMed Journal: Acta Crystallogr C ISSN： 0108-2701 Impact factor: 1.172

Keyword Cloud
Cited

1 in total

1. Effect of the Ruffled Porphyrin Ring on Electronic Structures: Structure and Characterization of [Fe(TalkylP)(OClO₃)] and [Fe(TPrP)(THF)₂]ClO₄ (alkyl = Ethyl, Et and n-Propyl, Pr).

Authors: Ming Li; Allen G Oliver; Teresa J Neal; Charles E Schulz; W Robert Scheidt
Journal: J Porphyr Phthalocyanines Date: 2013-01 Impact factor: 1.811

1 in total

Molecular stereochemistry of [FeIII(TPP)(OCOCF3)].

1. Effect of the Ruffled Porphyrin Ring on Electronic Structures: Structure and Characterization of [Fe(TalkylP)(OClO3)] and [Fe(TPrP)(THF)2]ClO4 (alkyl = Ethyl, Et and n-Propyl, Pr).

1. Effect of the Ruffled Porphyrin Ring on Electronic Structures: Structure and Characterization of [Fe(TalkylP)(OClO₃)] and [Fe(TPrP)(THF)₂]ClO₄ (alkyl = Ethyl, Et and n-Propyl, Pr).