| Literature DB >> 8415759 |
J van Elp1, S J George, J Chen, G Peng, C T Chen, L H Tjeng, G Meigs, H J Lin, Z H Zhou, M W Adams.
Abstract
Soft x-ray magnetic circular dichroism was used to study a paramagnetic bioinogranic system. We measured the Fe L edges of Pyrococcus furiosus rubredoxin, using circularly polarized synchrotron radiation, a split-coil super-conducting magnet, low sample temperatures, and fluorescence detection. The observed dichroism effect is strong (30%) and in general agreement with the calculation. The method is element- and oxidation state-specific, and the data can be interpreted by established theoretical procedures. Soft x-ray magnetic circular dichroism demonstrates enormous potential as a probe for studying paramagnetic systems in biology, chemistry, and material science.Entities:
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Year: 1993 PMID： 8415759 PMCID： PMC47630 DOI： 10.1073/pnas.90.20.9664
Source DB: PubMed Journal: Proc Natl Acad Sci U S A ISSN： 0027-8424 Impact factor: 11.205