Literature DB >> 7986660

The interaction of the vanadyl (IV) cation with chondroitin sulfate A.

S B Etcheverry1, P A Williams, E J Baran.   

Abstract

The interaction of VO2+ with the muchopolysaccharide chondroitin sulfate A (CSA) has been investigated by electron absorption spectroscopy and infrared measurements in aqueous solutions at different pH-values and ligand to metal ratios up to 6:1. The generation of a VO(CSA)2 species could be demonstrated. Coordination of the oxocation through the carboxylate group and the glycosidic oxygen of the D-glucuronate moieties is suggested. Infrared spectra of some poorly characterized solid VO/CSA complexes point to the same bonding characteristics. Preliminary results obtained at higher ligand to metal ratios suggest a different coordination behavior.

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Year:  1994        PMID： 7986660     DOI： 10.1007/BF02990487

Source DB:  PubMed          Journal:  Biol Trace Elem Res        ISSN： 0163-4984            Impact factor:   3.738


  8 in total

Review 1.  Structure and function of vanadium compounds in living organisms.

Authors:  D Rehder
Journal:  Biometals       Date:  1992       Impact factor: 2.949

2.  Infra-red spectroscopic studies of some polysaccharides.

Authors:  S F ORR
Journal:  Biochim Biophys Acta       Date:  1954-06

3.  Cu2+-hyaluronic acid complex: spectrophotometric detection.

Authors:  N Figueroa; B Nagy; B Chakrabarti
Journal:  Biochem Biophys Res Commun       Date:  1977-01-24       Impact factor: 3.575

4.  A model study of the incorporation of vanadium in bone.

Authors:  S B Etcheverry; M C Apella; E J Baran
Journal:  J Inorg Biochem       Date:  1984-04       Impact factor: 4.155

5.  Calcium chondroitin 4-sulfate: molecular conformation and organization of polysaccharide chains in a proteoglycan.

Authors:  J J Cael; W T Winter; S Arnott
Journal:  J Mol Biol       Date:  1978-10-15       Impact factor: 5.469

6.  A 13C-n.m.r. study of the binding of ytterbium(III) to chondroitin sulphate and chondroitin.

Authors:  S Balt; M W de Bolster; G Visser-Luirink
Journal:  Carbohydr Res       Date:  1983-09-16       Impact factor: 2.104

7.  Binding of metal ions to polysaccharides. V. Potentiometric, spectroscopic, and viscosimetric studies of the binding of cations to chondroitin sulfate and chondroitin in neutral and acidic aqueous media.

Authors:  S Balt; M W de Bolster; M Booij; A M van Herk; G Visser-Luirink
Journal:  J Inorg Biochem       Date:  1983-11       Impact factor: 4.155

8.  Investigation of the hyaluronic acid-copper complex by N.M.R. spectroscopy.

Authors:  H Sterk; M Braun; O Schmut; H Feichtinger
Journal:  Carbohydr Res       Date:  1985-12-15       Impact factor: 2.104
  8 in total
  1 in total

1.  A spectroscopic study of the interaction of the VO2+ cation with the two components of chondroitin sulfate.

Authors:  S B Etcheverry; P A Williams; E J Baran
Journal:  Biol Trace Elem Res       Date:  1996-02       Impact factor: 3.738
  1 in total

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