Further studies on new furostanol saponins from the bulbs of Allium macrostemon.

Further studies by means of preparative HPLC led to the isolation of two new furostanol saponins, macrostemonoside J (1) and L (3), along with an artifact, macrostemonoside K (2) from the bulbs of Allium macrostemon. On the basis of chemical evidence and spectral analysis (1H-, 13C-NMR and FAB-MS), the structure of 1 was elucidated to be 26-O-beta-D-glucopyranosyl 2 beta,3 beta,22,26-tetrahydroxy-25(R)-5 beta-furostan 3-O-beta-D-glucopyranosyl (1-->2)-beta-D-galactopyranoside. 3 was deduced to be 26-O-beta-D-glucopyranosyl 2 beta,3 beta,26-trihydroxy-25(R)-5 beta-furostan- 20(22)-ene 3-O-beta-D-glucopyranosyl (1-->2)-beta-D-galactopyranoside.